Malik, P (2010) Investigation on Tautomeric Equilibrium of Schiff Base in Mixed Binary Solvent. MSc thesis.
Enol imine- keto inamine tautomeric equilibrium has been studied in bis-salicilidene schiff base (sal-en-Sal) with a spacer unit in aqueous-organic binary solvent mixture. Organic solvent favors the E-form (enol form) while aqueous solvent favors both the E-form and K-form (keto form). The binary solvent mixture has a transition at almost 70% volume of organic solvent. i.e. the non-aqueous solvent molecules remain within water clusters upto a volume percentage of almost 70, beyond which the water clusters remain in the oil framework. The tautomeric equilibrium is very sensitive to water.
|Item Type:||Thesis ( MSc)|
|Uncontrolled Keywords:||bis-salicilidene schiff base, Binary solvent mixture, Enol imine- keto inamine tautomerism|
|Subjects:||Chemistry > Organic Chemistry|
|Divisions:||Sciences > Department of Chemistry|
|Deposited By:||Prakash Malik|
|Deposited On:||10 May 2010 14:16|
|Last Modified:||10 May 2010 14:16|
Repository Staff Only: item control page