Sethy, Sangeeta (2012) Synthesis and Characterization of Oxovanadium Complexes Incorporating Bidentate ligand. MSc thesis.
Two new oxovanadium(V) complexes, [VO(L1I)2(OEt)] and [VO(L2S)2(OEt)] (1-2) have been reported which are obtained from the reaction of the Schiff bases (L1IH1, L2SH1), (Where L1IH1 = isonicotinylhydrazone of benzaldehyde, L2SH1 = salicylalhydrazone of acetophenone) with VO(acac)2 / VOSO4 in 2:1 molar ratio. All the synthesized ligands and the metal complexes are successfully characterized by elemental analysis, IR, UV-vis and NMR spectroscopy. This study indicates that both the complex (1 and 2) is monomeric in solid state while complex 2 may have dimeric nature in solution.
|Item Type:||Thesis ( MSc)|
|Uncontrolled Keywords:||Vanadium, Schiff base, ethanol,spectroscopy data|
|Subjects:||Chemistry > Inorganic Chemistry|
|Divisions:||Sciences > Department of Chemistry|
|Deposited By:||sethy sangeeta|
|Deposited On:||07 May 2012 10:51|
|Last Modified:||07 May 2012 10:51|
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